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Laboratoire de Spectroscopie Moléculaire de Surface
Yves Caudano


Spectroscopic studies of H-decorated interstitials and vacancies in thin-film silicon exfoliation

Y.J. Chabal (1), M.K. Weldon (1), Y. Caudano (2), B.B. Stefanov (1), and K. Raghavachari (1)
Physica B : Condensed Matter 273-274 (1999) 152-163


In this paper, we review the pivotal role that defects (in particular vacancy structures) play in driving the H-induced exfoliation of Si. We highlight the central role that infrared spectroscopy has played in delineating the microscopic details of the exfoliation process. We show that when the results of such spectroscopic studies are combined with those obtained using a variety of other experimental probes as well as ab initio quantum chemical cluster calculations, an unambiguous mechanistic picture emerges. Specifically we find that H-terminated vacancy structures drive the formation of internal surfaces into cracks where H2 is then evolved, resulting in the build-up of sufficient internal pressure to cause lift-off of the overlying Si. The role of co-implantation of He is also discussed.

Author addresses

  1. Bell Laboratories - Lucent Technologies
    600 Mountain Avenue, Murray Hill, NJ 07974, USA

  2. Laboratoire de Spectroscopie Moléculaire de Surface (LASMOS)
    Institute for Studies in Interface Science (ISIS)
    Facultés Universitaires Notre-Dame de la Paix (FUNDP)
    61 Rue de Bruxelles, B-5000 Namur, Belgium

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